Properties of Polymers:
The physical properties of a polymer, such as its strength and flexibility depend on:
Chain length - in general, the longer the chains the stronger the polymer;
Side groups - polar side groups give stronger attraction between polymer chains, making the polymer stronger;
Branching - straight, unbranched chains can pack together more closely than highly branched chains, giving polymers that are more crystalline and therefore stronger;
Cross-linking - if polymer chains are linked together extensively by covalent bonds, the polymer is harder and more difficult to melt.