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Geometrical Isomerism:
Isomers are two molecules
with the same molecular formula, but differ in the way the atoms are
arranged. Geometrical isomers are one form of stereoisomers
which have identical molecular formulae, the atoms are bonded
together in the same order but the arrangement of atoms in space are
different. Optical isomers are another form of stereoisomers.
Geometrical isomerism is also called cis-trans isomerism.
Cis-trans isomers occur
in organic compounds which contain a carbon-carbon double or triple
bond. An example is in but-2-ene.
The cis form is where the
substituent groups are on the same side of the double bond. The
trans form is where they on opposite sides.
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