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Conducting Polymers:
Alkynes are
hydrocarbons which contain a carbon-carbon triple bond, e.g.
ethyne (C2H2):
H - C
C -
H.
When ethyne is
polymerised, the product contains alternating single and double
bonds. Due to geometrical isomerism, two forms of polyethyne are
produced: cis-polyethyne and trans-polyethyne. By using a Ziegler-Natta
catalyst it was possible to produce just the cis form which on
warming was found to conduct electricity.
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